Write a balanced half-reaction for the reduction of solid manganese dioxide to manganese ion in acidic aqueous solution. be sure to add physical state symbols where appropriate.

Refrigerant-134a flows through a carnot heat pump cycle at 0.5 kg/s. it is known that the maximum absolute temperature in the cycle is 1.1 times the minimum absolute temperature, and the net power input to the cycle is 2.5 kw. if the refrigerant changes from a saturated vapor to a saturated liquid during the heat rejection process, determine the maximum magnitude of the enthalpy of vaporization for this process in kj/kg (with 3 significant figures).