Calculate the number of joules released when 72.5 grams of water at 95.0 degrees celsius cools to a final temperature of 28.0 degrees celsius.

Water's specific heat capacity is 4200 J/Kg°C
95-28=67
72.5grams in kg is 0.0725kg
Energy = 67×0.0725×4200
Energy = 20,401.5 J or 20.4015 kJ

Answer is: the equilibrium  shifts toward the reactants, to the left side of chemical reaction.it is because lead(ii) nitrate dissociates in water: pb(no₃)₂ → pb²⁺(aq) + 2no₃⁻(aq).according to lechatelier's principle, the position of equilibrium moves to counteract thechange (more lead cations, common ion), the position of equilibrium will move so that the concentration ofproducts decrease and concentration of reactants of chemical reaction increase.read more on -