HELP PLEASE lol, I just need a couple answers but I can't find this one anywhere, pic of question down below. :)

The balanced chemical equation for this lab is: 3cucl2(aq) + 2al(s) 3cu(s) + 2alcl3(aq) if 10.5 g copper chloride react with 12.4 g aluminum, what is the limiting reactant?

Some liquids can be distilled, but only at temperatures that are so high that it is impractical, or so high the compound decomposes. explain why distillation such compounds at significantly less than atmospheric pressure (some degree of vacuum) would solve this problem.

Kp is the equilibrium constant for dissociation of the propionic acid dimer. what is the sign of the slope for a plot of the natural logarithm of kp vs. inverse temperature for this reaction?