19.1-21. effect of a slow reaction rate on diffusion. gas a diffuses from point 1 to a catalyst surface at point 2, where it reacts as follows: 2a → b. gas b diffuses back a distance δ to point 1. derive the equation for na for a very fast reaction using mole fraction units xa1, and so on. for dab = 0.2 × 10–4m2/s, xa1 = 0.97, p = 101.32 kpa, δ = 1.30 mm, and t = 298 k, solve for na. do the same as in part (a) but for a slow first-order reaction where k1′ is the reaction velocity constant. calculate na and xa2 for part (c) where k1′=0.53×10−2m/s.

Astudent is given a sample of a blue copper sulfate hydrate. he weighs the sample in a dry covered porcelain crucible and got a mass of 23.875 g for the crucible, lid, and sample. the mass of the empty crucible and lid was found earlier to be 22.652 g. he then heats the crucible to expel the water of hydration, keeping the crucible at red heat for 10 minutes with the lid slightly ajar. on colling, he finds the mass of crucible, lid, and contents to be 23.403 g. the sample was changed in the process to very light clue anhydrous cuso4. if there are again 100.0 g of hydrate, how many grams of cuso4 are in it? how many moles of cuso4? (hint: molar mass of cuso4 = 159.6 g / mole. what per cent of the hydrate is cuso4? you may convert the mass of cuso4 to moles.)

Part b: study of equilibrium on solubility: mg(oh)2(s) ⇌ mg2+(aq) + 2 oh–(aq) cloudy clear (pink) 7. a. b. 8. a. b. 9. 10. 11. 12. when adding concentrated hydrochloric acid, how did the appearance of the equilibrium mixture change? the change in appearance indicated a shift in the point of equilibrium. in which direction did the equilibrium shift? (l) left (r) right explain your answer to question 7a. you should indicate which ion was added to or removed from the equilibrium mixture. when adding edta, how did the appearance of the equilibrium mixture change? the change in appearance indicated a shift in the point of equilibrium. in which direction did the equilibrium shift? (l) left (r) right explain your answer to question 8a. you should indicate which ion was added to or removed from the equilibrium mixture. upon heating in which direction is the equilibrium shifting? upon cooling in which direction is the equilibrium shifting? is the forward reaction a. endothermic explain your answers to questions 9, 10, and 11. (l) left (r) right (l) left (r) right b. exothermic

Which of the following contributes to the structural rigidity of cellulose? adjacent glucose polymers are stabilized by hydrogen bonding. glucose residues are joined by (α1→4) linkages. cellulose is a highly branched molecule. the conformation of the glucose polymer is a coiled structure.