Help? i’m really confused by this

If 2 moles of co_2 at 2l and 500k are expanded reversibly to 20l, more work can be obtained from an adiabatic process than from an isothermal process. is the above statement true or false?

As you are trying to move a heavy box of mass m, you realize that it is too heavy for you to lift by yourself. there is no one around to , so you attach an ideal pulley to the box and a massless rope to the ceiling, which you wrap around the pulley. you pull up on the rope to lift the box. use g for the magnitude of the acceleration due to gravity and neglect friction forces. once you have pulled hard enough to start the box moving upward, what is the magnitude f of the upward force you must apply to the rope to start raising the box with constant velocity? express the magnitude of the force in terms of m, the mass of the box.

Consider an insulating crystal, made up of layers of atoms. what form would you expect the temperature dependence of the phonon heat capacity to approach at extremely low temperatures if the interlayer coupling is i)very strong (rigid coupling), and ii) very weak. explain.