Someone give me the answer to this

Can someone explain to me how to do this problem ?

5g of ammonium nitrate was dissolved in 60g of water in an insulated container. the temperature at the start of the reaction was 23.0°c and at the end it was 19.0°c. calculate the energy absorbed by the reaction.

Water is siphoned from a large tank and discharges into the atmosphere through a 50-mm diameter tube. the end of the tube is b = 2.1 m below the tank bottom which is a = 7.4 m deep, and viscous effects are negligible. determine the maximum height h over which the water can be siphoned without cavitation occurring. atmospheric pressure is 101.4 kpa, and the water vapor pressure is 1.79 kpa (absolute)