Physics, 30.07.2021 05:10 AgentPangolin

Consider a box with two gases separated by an impermeable membrane. The membrane can move back and forth, but the gases cannot penetrate the membrane. The left side is filled with gas A and the right side is filled with gas B. We will assume that equipartition applies to both gases, but gas A has an excluded volume due to large molecules so its entropy has a different formula. SA=NAkln(VA+ bNA)+f(UA, NA)
SB=NBkln(VB)+f(UB, NB)

Required:
If NA= 1 moles, NB = 2 moles, the total volume of the box is 1 m3, and b= 4 × 10-4 m3/mole, then find the equilibrium value of VA by maximizing the total entropy.

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Consider a box with two gases separated by an impermeable membrane. The membrane can move back and f...