Electrical breakdown
Materials are often classified as conductors or insulators based on their resistivity. A conductor is a substance which contains many mobile charged particles called charge carriers which are free to move about inside the material. An electric field is created across a piece of the material by applying a voltage difference between electrical contacts on different sides of the material. The force of the field causes the charge carriers within the material to move, creating an electric current from the positive contact to the negative contact. For example, in metals one or more of the negatively charged electrons in each atom, called conduction electrons are free to move about the crystal lattice. An electric field causes a large current to flow, so metals have low resistivity, making them good conductors. In contrast in materials like plastics and ceramics all the electrons are tightly bound to atoms, so under normal conditions there are very few mobile charge carriers in the material. Applying a voltage causes only a very small current to flow, giving the material a very high resistivity, and these are classed as insulators.
However, if a strong enough electric field is applied, all insulators become conductors. If the voltage applied across a piece of insulator is increased, at a certain electric field the number of charge carriers in the material suddenly increases enormously and its resistivity drops, causing a strong current to flow through it. This is called electrical breakdown. Breakdown occurs when the electric field becomes strong enough to pull electrons from the molecules of the material, ionizing them. The released electrons are accelerated by the field and strike other atoms, creating more free electrons and ions in a chain reaction, flooding the material with charged particles. This occurs at a characteristic electric field strength in each material, measured in volts per centimeter, called its dielectric strength.
When a voltage is applied across a piece of insulator, the electric field at each point is equal to the gradient of the voltage. The voltage gradient may vary at different points across the object, due to its shape or local variations in composition. Electrical breakdown occurs when the field first exceeds the dielectric strength of the material in some region of the object. Once one area has broken down and become conductive, that area has almost no voltage drop and the full voltage is applied across the remaining length of the insulator, resulting in a higher gradient and electric field, causing additional areas in the insulator to break down. The breakdown quickly spreads in a conductive path through the insulator until it extends from the positive to the negative contact. The voltage at which this occurs is called the breakdown voltage of that object. Breakdown voltage varies with the material composition, shape of an object, and the length of material between the electrical contacts.
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