Why do buildings on permafrost have potential structural issues?

In the derivation of rrkm theory, a factor of 1/2 is introduced when equalizing the rates of formation and decomposition of activated complex as keal-hr) = ko this is clearly against the assumption of transition state theory that states all the activated complex in the transition state iss going to the product. find the reason why this factor is introduced here.

If a refrigerator is a heat pump that follows the first law of thermodynamics, how much heat was removed from food inside of the refrigerator if it released 380j of energy to the room?

Asquare 1m x 1m plate is shown below. all four of its edges are kept at 0 co. at t=0the temperature distribution is given by: y xtsins n75)=.a) using separation of variables determine the temperature distribution t(x, y,t)along the plate at any time t. b) discretize the heat conduction equation +=22222 txtusing a second-order centered difference scheme for the two second derivatives and a first-order forward euler scheme for the first derivative. using von neumann stability analysis, determine the stability criterion for the proposed discretization scheme in terms of , hand t. solve for the maximum allowable time step tmax