1. a sample consisting of 1.0 mol caco3 (s) was heated to 800oc when it is decomposed. the heating was carried out in a container fitted with a piston that was initially resting on the solid. calculate the work done during complete decomposition at 1.0 atm. what work would be done if instead of having a piston, the container was open to the atmosphere?

Consider the particle-in-a-box problem in 1d. a particle with mass m is confined to move freely between two hard walls situated at x = 0 and x = l. the potential energy function is given as (a) describe the boundary conditions that must be satisfied by the wavefunctions ψ(x) (such as energy eigenfunctions). (b) solve the schr¨odinger’s equation and by using the boundary conditions of part (a) find all energy eigenfunctions, ψn(x), and the corresponding energies, en. (c) what are the allowed values of the quantum number n above? how did you decide on that? (d) what is the de broglie wavelength for the ground state? (e) sketch a plot of the lowest 3 levels’ wavefunctions (ψn(x) vs x). don’t forget to mark the positions of the walls on the graphs. (f) in a transition between the energy levels above, which transition produces the longest wavelength λ for the emitted photon? what is the corresponding wavele

While standing outdoors one evening, you are exposed to the following four types of electromagnetic radiation: yellow light from a sodium street lamp, radio waves from an am radio station, radio waves from an fm radio station, and microwaves from an antenna of a communications system. rank these type of waves in terms of increasing photon energy.

Your starship, the aimless wanderer, lands on the mysterious planet mongo. as chief scientist-engineer, you make the following measurements: a 2.50-kg stone thrown upward from the ground at 14.0 m/s returns to the ground in 5.70 s ; the circumference of mongo at the equator is 2.20×10^5 km ; and there is no appreciable atmosphere on mongo. (a) the starship commander, captain confusion, asks for the following information: what is the mass of mongo? (b) if the aimless wanderer goes into a circular orbit 2.20×10^4 km above the surface of mongo, how many hours will it take the ship to complete one orbit? (c) an unmanned spacecraft is in a circular orbit around the moon, observing the lunar surface from an altitude of 44.0 km . to the dismay of scientists on earth, an electrical fault causes an on-board thruster to fire, decreasing the speed of the spacecraft by 23.0 m/s . if nothing is done to correct its orbit, with what speed (in km/h) will the spacecraft crash into the lunar surface?