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Consider the particle-in-a-box problem in 1d. a particle with mass m is confined to move freely between two hard walls situated at x = 0 and x = l. the potential energy function is given as (a) describe the boundary conditions that must be satisfied by the wavefunctions ψ(x) (such as energy eigenfunctions). (b) solve the schr¨odinger’s equation and by using the boundary conditions of part (a) find all energy eigenfunctions, ψn(x), and the corresponding energies, en. (c) what are the allowed values of the quantum number n above? how did you decide on that? (d) what is the de broglie wavelength for the ground state? (e) sketch a plot of the lowest 3 levels’ wavefunctions (ψn(x) vs x). don’t forget to mark the positions of the walls on the graphs. (f) in a transition between the energy levels above, which transition produces the longest wavelength λ for the emitted photon? what is the corresponding wavele

Amoving electron has kinetic energy k1. after a net amount of work w has been done on it, the electron is moving one-quarter as fast in the opposite direction. (a) find w in terms of k1. (b) does your answer depend on the final direction of the electron's motion?

Nacidified solution was electrolyzed using copper electrodes. a constant current of 1.18 a caused the anode to lose 0.584 g after 1.52 ✕ 103 s. given that the charge of an electron is 1.6022 ✕ 10−19 c, calculate avogadro's number. assume that copper is oxidized to cu2+ ions.