Which refers to the change of pitch heard when the source of the sound approaches and then moves away from a stationary person? Doppler effect volume resonance effect vibration

Asmall electric heater, immersed in 80g of water in a calorimeter of 40j/k raises the temperature from 10.5 degree celsius to 25 degree celsius in 12 minutes. using the same apparatus with 50g of oil instead of water, it is found that the temperature of oil rises from 7 degree celsius to 27 degree celsius in 10 minutes. find specific heat capacity of the oil.