What are the good absorber of heat

In the derivation of rrkm theory, a factor of 1/2 is introduced when equalizing the rates of formation and decomposition of activated complex as keal-hr) = ko this is clearly against the assumption of transition state theory that states all the activated complex in the transition state iss going to the product. find the reason why this factor is introduced here.

Argon is adiabatically compressed from an initial volume of 16 liters to a final volume of 2 liters. by what factor do the following quantities change? do they increase or decrease? (a) the rms speed (b) the thermal energy of the gas (c) the molar specific heat cv (d) the pressure

Arunner is jogging at a steady 3.6 km/hr. when the runner is 2.9 km from the finish line, a bird begins flying from the runner to the finish line at 14.4 km/hr (4 times as fast as the runner). when the bird reaches the finish line, it turns around and flies back to the runner. even though the bird is a dodo, we will assume that it occupies only one point in space, i. e., a zero-length bird. how far does the bird travel? (b) after this first encounter, the bird then turns around and flies from the runner back to the finish line, turns around again and flies back to the runner. the bird repeats the back and forth trips until the runner reaches the finish line. how far does the bird travel from the beginning? (i. e. include the distance traveled to the first encounter)