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The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

The vapour pressure of benzene is 53.3 kpa at 60.6 °c, but it fell to 51.5 kpa when 19.0 g of a non-volatile organic compound was dissolved in 500 g of benzene. calculate the molar mass of the compound.

The magnitude of the poynting vector of a planar electromagnetic wave has an average value of 0.939 w/m^2 . the wave is incident upon a rectangular area, 1.5 m by 2.0 m, at right angles. how much total electromagnetic energy falls on the area during 1.0 minute?