Compressed gases aren't ideal. Let's consider a gas that's non-ideal only because the volume available to each of the N molecules is reduced because each other molecule occupies volume v. Instead of pV=NkT, we get: p(V-Nb)=NkT. Let b=1.2 × 10-28 m3. Let's look at 3moles of this gas at T=300K starting in 0.001 m3 volume. 1) What's the initial value of the pressure?

Jason is a body builder. despite being more fit, he weighs more than his brother ryan, who is the same height. which is a possible reason? a. jason has more muscle mass than ryan does. b. jason has more body fat than ryan does. c. jason has more muscle mass and body fat than ryan does d. jason has less body fat than ryan does.

We want to calculate the total metabolic heat generated by a singing canary taking into account heat transfer by radiation, convection and exhaling air. the air temperature is 20 oc, canary’s body internal and surface temperature is 33oc, external body surface convective heat transfer coefficient is 25.2 w/m2 .k, temperature difference between the inhaled and exhaled air is 4.3 oc, the ventilation rate is 0.74 cc of air per second, specific heat of air is 1.0066 kj/kg. k and density of air is 1.16 kg/m3 . assume the canary’s body to be a cylinder with 7 cm diameter and 9 cm length, and heat exchange is from the side as well as the top and bottom of cylinder. calculate 1) the net rate of heat lost by radiation, assuming heat gained by the bird through radiation from the surroundings is 11.5 w; 2) rate of heat transferred by convection to the surrounding air; 3) rate of heat transferred in the exhaling air without considering any internal evaporation; 4) total metabolic power.

Consider the particle-in-a-box problem in 1d. a particle with mass m is confined to move freely between two hard walls situated at x = 0 and x = l. the potential energy function is given as (a) describe the boundary conditions that must be satisfied by the wavefunctions ψ(x) (such as energy eigenfunctions). (b) solve the schr¨odinger’s equation and by using the boundary conditions of part (a) find all energy eigenfunctions, ψn(x), and the corresponding energies, en. (c) what are the allowed values of the quantum number n above? how did you decide on that? (d) what is the de broglie wavelength for the ground state? (e) sketch a plot of the lowest 3 levels’ wavefunctions (ψn(x) vs x). don’t forget to mark the positions of the walls on the graphs. (f) in a transition between the energy levels above, which transition produces the longest wavelength λ for the emitted photon? what is the corresponding wavele