Which one of the following represents an acceptable set of quantum numbers for an electron in an atom? (arranged as n, l, m l , and ms ) Which one of the following represents an acceptable set of quantum numbers for an electron in an atom? (arranged as n, l, m l , and ms ) 4, 4, 4, 1/2 4, 3, -3, 1/2 4, 3, 0, 0 4, 5, 7, -1/2 4, 4, -5, 1/2

The correct set of quantum numbers is 4, 3, -3, 1/2.

In chemistry, there are are four sets of quantum numbers that describe electrons in atoms and they are;

Usually, the principal quantum number n can take on integer values from 1 to infinity. The orbital quantum number takes on values from 0 to n - 1. The magnetic quantum number takes on values of -l to +l while the spin quantum number can only have values of ±1/2.

Having this behind our minds, we can see clearly that the only set of quantum numbers that satisfies the conditions stated above is the set; 4, 3, -3, 1/2. This arrangement corresponds to an electron in the 4f orbital.

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The correct option that represents an acceptable set of quantum numbers for an electron in an atom is;

(b) 4, 3, -3, 1/2.

Explanation:

To solve the question, we note that the available options where the set of quantum numbers for an electron in an atom are arranged as n, l, m l , and ms are;

4, 4, 4, 1/2

4, 3, -3, 1/2

4, 3, 0, 0

4, 5, 7, -1/2

4, 4, -5, 1/2

Let us label them as a to as follows

(a) 4, 4, 4, 1/2

(b) 4, 3, -3, 1/2

(c) 4, 3, 0, 0

(d) 4, 5, 7, -1/2

(e) 4, 4, -5, 1/2

Next we note the rules for the assignment and arrangement of quantum numbers are as follows

Number                                   Symbol                Possible values

Principal Quantum Number  .......n........................1, 2, 3, ......n

Angular momentum quantum

number...............................................l.........................0, 1, 2, .......(n - 1)

Magnetic Quantum Number........m₁......................-l, ..., -1, 0, 1,.....,l  

Spin Quantum Number.................m.....................+1/2, -1/2

We are meant to analyze each of the arrangement for acceptability.

Therefore for (a),

we note that the angular momentum quantum number, l =4 , is equal to the principal quantum number n =4 which violates the rule as the maximum value of the angular momentum quantum number is (n-1) where the maximum value of the principal quantum number is n.

Therefore (a) is not acceptable.

(b) Here we note that

The principal quantum number n = 4 ∈ (1, 2, 3, ......n) → acceptable

The angular momentum quantum number l = 3 ∈ (0, 1, 2, .......(n - 1)) → acceptable

The magnetic quantum number m₁ = -3 ∈ (-l, ..., -1, 0, 1,.....,l)  → acceptable

The spin quantum number m = 1/2 ∈ (+1/2, -1/2) → acceptable

Therefore (b) 4, 3, -3, 1/2 represents an acceptable set of quantum numbers for an electron in an atom.

(c) Here we have

The principal quantum number n = 4 ∈ (1, 2, 3, ......n) → acceptable

The angular momentum quantum number l = 3 ∈ (0, 1, 2, .......(n - 1)) → acceptable

The magnetic quantum number m₁ = 0 ∈ (-l, ..., -1, 0, 1,.....,l)  → acceptable

The spin quantum number m = 0 ∉ (+1/2, -1/2) → not acceptable

Therefore (c) 4, 3, 0, 0 does not represents an acceptable set of quantum numbers for an electron in an atom.

(d) Here we have;

The principal quantum number n = 4 ∈ (1, 2, 3, ......n) → acceptable

The angular momentum quantum number l = 5 ∉ (0, 1, 2, .......(n - 1)) → not acceptable

The magnetic quantum number m₁ = 7 ∉ (-l, ..., -1, 0, 1,.....,l)  → acceptable

The spin quantum number m = -1/2 ∈ (+1/2, -1/2) → acceptable

Therefore (d) 4, 5, 7, -1/2 does not represents an acceptable set of quantum numbers for an electron in an atom.

(e) Here we have;

The principal quantum number n = 4 ∈ (1, 2, 3, ......n) → acceptable

The angular momentum quantum number l = 4 ∉ (0, 1, 2, .......(n - 1)) → not acceptable

The magnetic quantum number m₁ = -5 ∉ (-l, ..., -1, 0, 1,.....,l)  → acceptable

The spin quantum number m = 1/2 ∈ (+1/2, -1/2) → acceptable

Therefore (e) 4, 4, -5, 1/2 does not represents an acceptable set of quantum numbers for an electron in an atom.

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