What pollutant forms when automobile emissions react with oxygen gas and ultraviolet rays?

Ozone is a molecule that consists of three oxygen atoms. When high-energy ultraviolet rays strike ordinary oxygen molecules (O2), they split the molecule into two single oxygen atoms, known as atomic oxygen. A freed oxygen atom then combines with another oxygen molecule to form a molecule of ozone.  Hydrocarbons and nitrogen oxides come from great variety of industrial and combustion processes. Motor vehicle exhaust and industrial emissions, gasoline vapors, and chemical solvents are some of the major sources of NOx and VOC that acts as a precursor of ozone. In urban areas, the number of automobiles are more and therefore, more production of such harmful gases. These gases in presence of sunlight leads to the formation of bad ozone.

object 2 because all the other ones are wrong

scattering of light by tiny particles in air to produce the colors we see on sky, is dependent on the following factors:

(i) wavelength of light

(ii) size of the scattering particle  

(iii) distance traveled by light through the atmosphere.

according to rayleigh's law of scattering, the amount of scattering is inversely proportional to the fourth power of its wavelength. shorter the wavelength, greater is its scattering. hence violet/blue light is scattered more than red.

sun's light is a composite light ( visible light) with wavelengths in the range 400 nm (violet) to 700 nm (red). as sunlight passes through our atmosphere, the molecules of air scatter light according to their wavelengths. during sunrise and sunset, the sun's position is below the horizon. hence light from the sun travels a greater distance in the atmosphere when compared to its position a noon.

as sunlight enters the earth's atmosphere, blue light is scattered away and at the end of its journey in the sky, only red and orange wavelengths remain in the beam.

hence at sunrise and sunset, the sky appears reddish orange.