By measuring the temperature change accompanying a differential volume change in a free expansion across a valve and separately in a reversible adiabatic expansion, the two derivatives (∂t/∂v )h and (∂t/∂v )s can be experimentally evaluated. a. develop expressions for these derivatives in terms of the more fundamental quantities. b. evaluate these derivatives for a van derwaals fluid.

true, as the earth rotates the sun hits the surface of the planet; causing the day and night cycle.

  the grams     of oxygen gas   that can be produced     is 20.6   grams of o₂

calculation

2liclo₃ →   2 licl + 3 o₂

step 1:   find the moles of liclo₃

moles = mass÷ molar mass

from periodic table the molar mass of liclo₃ =6.9 +35.5   +(16 x3) =90.4 g/mol

moles=38.7 g÷90.4 g/mol=0.4281   moles

step 2:   use the   mole ratio   to calculate the moles of o2

from equation above, liclo₃: o₂   is 2: 3  

therefore the moles of   o₂=0.4281 moles x3/2 =0.6422   moles

step 3: find mass   of o₂

mass= moles x molar mass

from periodic table the   molar mass of   o₂ = 16 x2= 32 g/mol

mass=0.6422   moles   x   32 g/mol = 20.6 grams of o₂

bacteria that live on the ocean floor are sustained by phytoplankton. phytoplankton, microscopic marine photosynthetic organisms, have a vastly significant role to play not only in the marine food web of which they’re part of, but also on a more global scale. despite their infinitely small size in comparison to other marine organisms, these tiny creatures occupy an immensely important ecological niche: they are the foundation of the marine food web, and as primary producers, play key roles in supporting all other organisms in the marine environment, as well as in the regulation of the earth’s climate through the sequestration of carbon, oxygen production, and other related processes. phytoplankton account for roughly half of all global primary productivity; therefore, their significance extends far beyond the marine environment alone. there is an intriguing sense of irony in the realization that these tiny living beings that often live out their existence unnoticed and undetected by the rest of the world, have such a far-reaching impact on the lives of virtually all other living organisms on the planet, particularly on those in the marine environment. the world that we have become accustomed to has been and is continuously shaped by the workings of these miniscule yet vital “plants of the sea”.

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