At some point as you are hiking near a lake, you determine that your campsite is 1.50 km away from you in the direction 30.0° e of n. however, to get back to your campsite, you will need to walk around the lake. you set off due north and walk for 600 m. you then turn in the direction 20.0 w of n and walk an addol1.20 km, before turning and walking directly to your campsite. how far and in what direction was the last leg of your hike?

The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

Search coils and credit cards. one practical way to measure magnetic field strength uses a small, closely wound coil called a search coil. the coil is initially held with its plane perpendicular to a magnetic field. the coil is then either quickly rotated a quarter-turn about a diameter or quickly pulled out of the field. (a) derive the equation relating the total charge q that flows through a search coil to the magnetic-field magnitude b. the search coil has n turns, each with area a, and the flux through the coil is decreased from its initial maximum value to zero in a time ∆t. the resistance of the coil is r, and the total charge is q = i∆t, where i is the average current induced by the change in flux. (b) in a credit card reader, the magnetic strip on the back of a credit card is rapidly “swiped” past a coil within the reader. explain, using the same ideas that underlie the operation of a search coil, how the reader can decode the information stored in the pattern of magnetization on the strip. (c) is it necessary that the credit card be “swiped” through the reader at exactly the right speed? why or why not?

How to tell if a molecule is polar or nonpolar with electronegativity