The second law of thermodynamics leads us to conclude that

In the derivation of rrkm theory, a factor of 1/2 is introduced when equalizing the rates of formation and decomposition of activated complex as keal-hr) = ko this is clearly against the assumption of transition state theory that states all the activated complex in the transition state iss going to the product. find the reason why this factor is introduced here.

Clothing made of several thin layers of fabric with trapped air in between, often called ski clothing, is commonly used in cold climates because it is light, fashionable, and a very effective thermal insulator. so it is no surprise that such clothing has largely replaced thickand heavy old-fashioned coats. (a) consider a jacket made of five layers of 0.1-mm-thick synthetic fabric (k = 0.13 w/m·°c) with 1.5-mm-thick air space (k = 0.026 w/m·°c) between the layers. assuming the inner surface temperature of the jacket to be 28°c and the surface area to be 1.25 m2, determine the rate of heat loss through the jacket when the temperature of the outdoors is 0°c and the heat transfer coefficient at the outer surface is 25 w/m2·°c. (b) what would your response be if the jacket is made of a single layer of 0.5-mm-thick synthetic fabric? what should be the thickness of a wool fabric (k = 0.035 w/m·°c) if the person is to achieve the same level of thermal comfort wearing a thick wool coat instead of a five-layer ski jacket?

At a certain instant after jumping from the airplane a, a skydiver b is in the position shown and has reached a terminal (constant) speed vb = 52 m/s. the airplane has the same constant speed va = 52 m/s, and after a period of level flight is just beginning to follow the circular path shown of radius ρa = 2330 m. (a) determine the velocity and acceleration of the airplane relative to the skydiver. (b) determine the time rate of change of the speed vr of the airplane and the radius of curvature ρr of its path, both as observed by the nonrotating skydiver.