Pls help ASAP I only have 10 minutes there’s two questions! Pls help!!

The ratio pv to nrt is plotted against pressure for ch4 at 0°c and 200°c. why does the curve for 0°c drop below the horizontal line for an ideal gas whereas the curve for 200°c does not?

Each month, a shopkeeper spends 5x + 14 dollars on rent and electricity. if he spends 3x−5 dollars on rent, how much does he spend on electricity? for which value(s) of x is the amount the shopkeeper spends on electricity less than $100? explain how you found the value(s).

(-y to the power of 2 - 4y- to the power of 2 -6 y +3)