In desperate need of help , please help lol

(a) calculate the molarity of a solution that contains 0.0345 mol nh4cl in 400 ml of solution. (b) how many moles of hno3 are present in 35.0 ml of a 2.20 m solution of nitric acid? (c) how many milliliters of 1.50 m koh solution are needed to supply 0.125 mil of koh ?

Money off coupons have been circulated to 300 households. only 2/5 of these were redeemed (used) in the local supermarket to get a free shampoo. what fraction of coupons were unused? (ps: write how you got the answer)

Pls as soon as ! will award brainliest and 20 ! also the answer is not 22.5 degrees! find the value of x in each case: