Which of these measures was specifically designed to limit the voting rights of the black freedmen?

The Voting Rights Act of 1965, signed into law by President Lyndon B. Johnson, aimed to overcome legal barriers at the state and local levels that prevented African Americans from exercising their right to vote as guaranteed under the 15th Amendment to the U.S. Constitution.

15th amendment is the answer.

the grandfather clause

- "the most famous structure by far at saqqara is djoser's step pyramid. dating from the 3rd dynasty (2667—2448 bc), it was the first all-stone complex ever built on earth."

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first industrial revolution - the first wave of the industrial revolution lasted from the late 1700s to the mid-1800s. it industrialized the manufacture of textiles and began the move of production from homes to factories. steam power and the cotton gin played an important role in this period.