Someone please help, I got this as an assignment Derive the Tds relations for an internally reversible/irreversible process on a unit mass
basis from the First and Second laws of thermodynamics.

Steel is coated with a thin layer of ceramic to protect against corrosion. what do you expect to happen to the coating when the temperature of the steel is increased significantly? explain.

Different types of steels contain different elements that alter the characteristics of the steel. for each of the following elements, explain what the element does when alloyed with steel.

For each of the following process: a) sketch the p-v diagram, b)sketch t-s diagram, c) sketch t-v diagram, d) sketch the boundary work on one of the diagrams (a, b or c) and e) sketch the reversible heat transfer on one of the diagrams (a, b or c): 1- isobaric process from compressed liquid to superheated vapor 2- isothermal process from compressed liquid to superheated vapor 3- isentropic process from compressed liquid to superheated vapor