Draw curved arrows to complete diels-alder mechanism for two reactants shown draw product of reaction

Define dew point. i am writing this part to be able to ask the question

The content of manganese (mn) in steel was determined spectrophotometrically and with the use of the standard addition method. an unknown sample of mn from a digested steel sample gave an absorbance of 0.185 when analyzed spectrophotometrically. when 5.00 ml of solution containing 95.5 ppm mn was added to 50.0 ml of the unknown steel solution (digested sample), the absorbance was 0.248. calculate the concentration, in parts-per-million (ppm), of mn in the digested steel sample solution.

Determine the ph of 0.10 m nh3 solution. nh3 is a weak base with a kb equal to 1.8 x 10-5 round answer to nearest whole number.