Sports trainers treat sprains and soreness with ethyl bromide. it is manufactured by reacting ethylene with hydrogen bromide:

Trainers use this substance because the reaction of the product on the skin is an exothermic one. This produces a feeling of warmth and heat. Heating an injury like a sprain with warmth or heat increases blood flow to the area and promotes healing as the flow of blood carries the necessary substances for healing. 

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☆ionisation energy increases across a period from na -> ar☆ionisation energy decreases down a group from li -> fr☆ionic radius decreases across a period from na -> cl☆ionic radius increases down a groupfrom f -> ii hope it clarifies your doubts