A solution of 0.0470 M HCl is used to titrate 26.0 mL of an ammonia solution of unknown concentration. The equivalence point is reached when 16.0 mL HCl solution have been added. (Assume KW = 1.01 e−14.) What was the pH at the equivalence point?

The pH at equivalence point is 12.46

At equivalence point, number of moles of acid, n equals number of moles of base, n'

So, n = n'

CV = C'V' where

Making C' subject of the formula, we have

C' = CV/V'

Substituting the values of the variables into the equation, we have

C' = CV/V'

C' = 0.0470 M × 16.0 mL/26.0 mL

C' = 0.752 MmL/26.0 mL

C' = 0.0289 M

We know that the ion-product of water Kw is

Kw = [H⁺][OH⁻] =  where

Making [H⁺] subject of the formula, we have

[H⁺} = Kw/[OH⁻]

[H⁺] = 1.01 × 10⁻¹⁴/0.0289

[H⁺] = 34.95 × 10⁻¹⁴

[H⁺] = 3.495 × 10⁻¹³

Since pH = -㏒[H⁺]

pH = -㏒[3.495 × 10⁻¹³]

pH = -㏒[3.495] + (-㏒10⁻¹³)

pH = -㏒[3.495] + [-13(-㏒10)]

pH = 13 - 0.5434

pH = 12.4566

pH ≅ 12.46

So, the pH at equivalence point is 12.46

Learn more about pH at equivalence point here:

the molecules move in straight line until they collide with each other or with the walls of the container. collisions are perfectly elastic; when two molecules collide, they change their directions and kinetic energies, but the total kinetic energy is conserved.

explanation:

both adhesion and cohesion are attractions.

they are different in that adhesion is the force of attraction between the molecules of two different substances, whereas cohesion is the force of attraction between molecules of the same substance.

possible examples include capillary action, in which the adhesion between water and glass causes the water to rise in a narrow tube against the force of gravity.

because of hydrogen bonding, water is extremely cohesive.

this causes molecules on the surface of water to be drawn inward, which is why drops of water form beads on smooth surfaces.

hope this .