Help please

24. a sports ball is inflated to an internal pressure of 1.85 atm at room temperature (25 °c). if the ball is then played with outside where the temperature is 7.5 °c, what will be the new pressure of the ball? assume the ball does not change in volume nor does any air leak from the ball a) 0.555 atm b) 1.74 atm c) 1.85 atm d) 1.97 atm

What is the ph of a solution that has a hydrogen ion concentration of 1.0 * 10 -9 m?

)benzene and toluene form nearly ideal solutions. consider an equimolar solution of benzene and toluene. at 20 °c the vapour pressures of pure benzene and toluene are 9.9 kpa and 2.9 kpa, respectively. the solution is boiled by reducing the external pressure below the vapour pressure. calculate (i) the pressure when boiling begins, (ii) the composition of each component in the vapour, and (iii) the vapour pressure when only a few drops of liquid remain. assume that the rate of vaporization is low enough for the temperature to remain constant at 20 °c.