At the equilibrium N2+3H2 = 2NH3, [NHz]=1M; after a catalyst is added to the equilibrium (NH3] will be increased.
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The activity series is shown in the attached picture. if the element is below the other, then you can displace the other. following the activity series as a guide, the reactions are as follows: nickel and aluminum chloride3 ni + 2 alcl₃  → 3 nicl₂ + 2 albarium and copper bromideba + cubr  →  no reaction because cu is less oxidizable than bapotassium nitrate and aluminum3 kno₃ + al  → al(no₃)₃ + 3 ksodium phosphate and zincnaso₄ + zn  → znso₄ + na

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Vander waals forces are inter molecular bonds that exist within molecules of the same substance. a water molecule is made up of oxygen and hydrogen atoms which share electrons between each other. the vander waals forces are forces that exist between multitude of different  molecules of water. dipole dipole forces is the type of vander waals force that exist in water. the oxygen atom which is more electronegative pulls the shared electron closer to itself thus generating a partial negative charge while the hydrogen acquire a partial positive charge. these two different charges causes attraction to occur in water molecules.