Why is it important to select a good stationary phase

The reaction q+r2=r2q is found to be first order in r2 and

Mary is conducting an experiment on how pollution affects plant growth. how can she ensure that her data are reliable?

Given the data below for the reaction, 2 a + 2 b + 4 c => d + e + 3 f, the reaction is fill in the [ ] order in a, fill in the [ ] order in b, fill in the [ ] order in c and fill in the [ ] order overall. (use the words "first, second, third, fourth" to fill each blank)experimentinitial conc of a, mol/l initial conc of b, mol/l initial conc of c, mol/l initial rate, mol/l. s1 0.1 0.1 0.2 2 x 10-32 0.2 0.3 0.2 6 x 10-33 0.3 0.1 0.2 2 x 10-34 0.4 0.3 0.4 1.2 x 10-2