Can someone plz help me :(

The boiling point of propanoic acid is higher than that of 1-butanol because: propanoic acid has a higher molecular weight than 1-butanol. propanoic acid is more soluble in water than 1-butanol. propanoic acid is a better hydrogen bond donor than 1-butanol. propanoic acid forms hydrogen bonded dimers and 1-butanol does not. 1-butanol forms hydrogen bonded dimers and propanoic acid does not.

All of the following are part of the biosphere except

Match the mixture with the substance// i really need on this guys (it’s a pic btw)