how to determine the aspects for core and valence electrons in a periodic table. How comes in some elements like cobalt the 3d is on the valence side and arsenic the 3d is on the core side.​

For neutral atoms, the number of valence electrons is equal to the atom's main group number. The main group number for an element can be found from its column on the periodic table. For example, carbon is in group 4 and has 4 valence electrons. Oxygen is in group 6 and has 6 valence electrons

For cyclohexane compounds drawn in a chair conformation:   -axial bonds are vertical  -equatorial bonds are parallel to two bonds within the ring.  thus, as i assume the chair conformation is drawn:   -the x group is in an axial position, as are the five other vertical bonds.  -three axial bonds are on the top face of the ring  -the other three axial bonds are on the bottom face  the position of the second substituent on each ring carbon is equatorial.  gauche groups must be on an adjacent carbon such as carbon 6 and carbon 2, and also gauche groups are rotated by 60 degrees relative to each other.  drawing the newman projections for c1–c2 and c1–c6 aids in visualizing the groups that are gauche to the y group on c1.  click this link and watch some academic videos that may you more understand the topic