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Thermal energy can increase even if the average kinetic energy is constant

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Iknow the answer to 13 is b and 14 is d. i just need to know why the correct answers are correct

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0.2348 grams of pbcl2 used to form 44.0 ml of solution.

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How much heat is added if 0.814g of water increase in temperature by 0.351 degree c?

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Thermal energy can increase even if the average kinetic energy is constant...

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