Identify the Lewis acid and Lewis base from among the reactants in each of the following equations. Part A
Ag+(aq)+2NH3(aq)⇌Ag(NH3)2+(aq)
a. Ag+ is the Lewis acid and NH3 is the Lewis base.
b. Ag+ is the Lewis base and NH3 is the Lewis acid.
Part B
AlBr3+NH3⇌H3NAlBr3
a. AlBr3 is the Lewis base and NH3 is the Lewis acid.
b. AlBr3 is the Lewis acid and NH3 is the Lewis base.
Part C
Cl−(aq)+AlCl3(aq)⇌AlCl4−(aq)
a. AlCl3 is the Lewis acid and Cl− is the Lewis base.
b. AlCl3 is the Lewis base and Cl− is the Lewis acid.

Part A

Ag+ is the Lewis acid and NH3 is the Lewis base.

Part B

AlBr3 is the Lewis acid and NH3 is the Lewis base.

Part C

AlCl3 is the Lewis acid and Cl− is the Lewis base.

Explanation:

A Lewis acid is any specie that accepts a lone pair of electrons. Ag^+, AlBr3 and AlCl3 all accepted lone pairs of electrons according to the three chemical reaction equations shown. Hence, they are Lewis acids.

A Lewis base donates a lone pair of electrons. They include neutral molecules having lone pair of electrons such as NH3 or negative ions such as Cl- .

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definition

                    entropy is a measure of the randomness or the extent of disorder of a chemical process.

                      enthalpy is a measure of the heat change of a reaction occurring at a constant pressure.

measurement units:

                        entropy is measured in joule per kelvin (jk⁻¹)   whereas enthalpy is measured in joule per mole (jmol⁻¹)

requirements:

                            entropy has no requirements or limits, and its change is measured by the division between the heat change of the chemical process and the temperature.

                              in contrast, enthalpy can only be related to the heat change of the reaction under standard conditions.