a deep underground cavern contains 2.24 x 10^6 L of methane (CH4) gas at a pressure of 15.0 atm and a temperature of 42 C. How many moles of methane does this natural gas deposit contain?

> b takes place in the gas phase in an isothermal tubular reactor. the feed is one mole of a per one mole of c, an inert. the entering temperature and pressure are 427°c and 10 atm, respectively. the gas constant r = 0.08206 atm · l/mol · k.

a). in this case, dh> 0 and sd> 0. if t becomes larger, the term "-tds" will become more negative. at some point, it is possible that -dts will be more negative than the dh is positive, and the reaction will become spontaneous. this is probably the correct answer, but you should look at all of the other possibilities and make sure of that.