How much energy is required to convert 32g of ice at –15⁰C to liquid water at 85⁰C?

Iknow #2 is d. i just need to know why

To save time, you can approximate the initial mass of the solid to the nearest ±1 g. for example, if you are asked to add 14.3 g of copper, add between 13 g and 15 g. which of the following sets include two samples with an equal density? which all that apply below 15.4 g gold and 18.7 g silver 15.2 g copper and 50.0 g copper 20.2 g silver and 20.2 g copper 11.2 g gold and 14.9 g gold

A3.37-mg sample of protein was chemically digested to convert its nitrogen into ammonia and then diluted to 100.0 ml. then 10.0 ml of this solution was placed in a 50-ml volumetric flask and treated with 5 ml of phenol solution plus 2 ml of sodium hypochlorite solution. the sample was diluted to 50.0 ml, and the absorbance at 625 nm was measured in a 1.00-cm cuvette and found to be 0.486. for reference, a standard solution was prepared from 10.0 mg of nh4cl (molar mass = 53.49 grams/mole) dissolved in 1.00 l of water. then 10.0 ml of this standard was placed in a 50-ml volumetric flask, treated in the same manner as the unknown, and the absorbance found to be 0.323. finally, a reagent blank was prepared using distilled water in place of unknown, it was treated in the same manner as the unknown, and the absorbance found to be 0.076. calculate the weight percent of nitrogen in the protein.