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Chemistry, 04.05.2021 22:10 ksteele1

When liquid Fe(CO)5 was first isolated, two structures were postulated, a C4v square pyramidal structure and a D3h trigonal bipyramidal structure. Using the 5 CO stretching vibrations as generating vectors in each of these point groups, generate the corresponding reducible representation, reduce each down to their respective irreps, and determine the symmetries of the IR and Raman active stretching vibrations. Required:
Using this information with knowledge of the experimental data, indicate the correct liquid phase structure of Fe(CO)5.

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When liquid Fe(CO)5 was first isolated, two structures were postulated, a C4v square pyramidal struc...

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