24. Chemical reactions occur around us every day. Combustion releases the carbon stored in fossil fuels (e. g. coal, oil, natural gases) into the atmosphere as carbon dioxide gas.
Which of the following equations represent this process?
A. C4H10 + O2 → CO2 + H2O
B. CO2 + H2O → C6H12O6 + O2
C. CaCO3 + HNO3 → Ca(NO3)2 + H2O + CO2
D. NaHCO3 + HC2H3O2 + NaC2H3O2 + H2O + CO2

at the bottom

explanation:

answer : (a) volume of the gas = 8.67 ×   l

                (b) second virial coefficient b = -1.21226 l/mole

solution :   given,     t = 300k

                                p = 20atm

                                z = 0.86

                                n = 8.2 mmoles = 8.2 × moles

                                r =   0.082 l atm/k/mol

        find,     (a) volume of gas   and (b) second virial coefficient b at 300k.

formula used :            

                          and            

(a)            

                    = \times 0.082\times 300}{20}[/tex]

                    = 8.67 ×   l

(b)      

                    = (0.00867-1) × 8.659

                    = - 8.5839 l/mole