Paul is trying to figure out the number of calories in a cube of cheese. To do this, she pours 169.6 mL of water into an aluminum can suspended from a ring stand. She takes the temperature of the water, and finds it to be 14.8 degrees Celsius. Then, she places the 5.23 gram cube of cheese under the can and lights it on fire! While the cheese is burning and for a few minutes after it is done, Carrie records the temperature of the water, finding that it levels out at 31.4 degrees Celsius. How many calories of heat were gained by the water? Please answer to the nearest 0.1 calorie.

Achemist at a pharmaceutical company is measuring equilibrium constants for reactions in which drug candidate molecules bind to a protein involved in cancer. the drug molecules bind the protein in a 1: 1 ratio to form a drug-protein complex. the protein concentration in aqueous solution at 25 ˚c is 1.74 x10-6 m . drug a is introduced into the protein solution at an initial concentration of 2.00 x10-6m. drug b is introduced into a separate, identical protein solution at an initial concentration of 2.00 x10-6m. at equilibrium, the drug a-protein solution has an a-protein complex concentration of 1.00 x10-6m, and the drug b solution has a b-protein complex concentration of 1.40 x10-6m. a. calculate the kc value for the a-protein binding reaction. b. calculate the kc value for the b-protein binding reaction. c. assuming that the drug that binds more strongly will be more effective, which drug is the better choice for further research?