Which of the following will dissolve the fastest

Iknow #2 is d. i just need to know why

Silver tarnishes as silver metal reacts with hydrogen sulfide, h2s, in the air. in this reaction, dark silver sulfide, au2s, covers the surface of silver. when silver is polished, this coating of silver sulfide can be removed from the surface. this makes the silver shiny again. enter the coefficients that balance the tarnishing reaction equation. (type 1 for no coefficient.)

8.98 dm3 of hydrogen gas is collected at 38.8 °c. find the volume the gas will occupy at -39.9 °c if the pressure remains constant.