How to turn a hot pocket into a weapon

Agas is contained in a thick walled balloon when the pressure changes from 1.21 atm to 2.52 the volume changes from 3.75 l to 1.72 l and the temperature change from 293k to blank k

Large helium-filled balloons are used to lift scientific equipment to high altitudes. what is the pressure inside such a balloon if it starts out at sea level with a temperature of 10.0ºc and rises to an altitude where its volume is twenty times the original volume and its temperature is – 50.0ºc ?

Δu of , in kj/kg, as it isto k, (a)as a of , (b) at , (c) at .