Plz help really struggling on these

The reactions shown here can be combined to make the overall reaction c(s) + h2o(g) ⇌ co(g) + h2(g) by reversing some and/or dividing all the coefficients by a number. a. c(s) + o2(g) → co2(g) k=1.363×10^69 b. 2 h2(g) + o2(g) → 2 h2o(g) k=1.389×10^80 c. 2co(g) + o2 (g) → 2 co2(g) k=1.477×10^90

3. how much energy in joules is required to evaporate .0005 kg of liquid ammonia to vapor at the same temperature? 4. how much energy ( in megajoules ) is given up by .75 kg of water at 0c when it freezes to form ice at 0c? 5. explain how heat works between and at critical temperatures?

In a heat engine of 1000 j of heat enters the system and the piston does 500 j of work what is the final internal energy of the system if the inital energy was 2000 j we have to do all of these down here 1)write the equation 2)list out your know variables 3)plug the numbers into the equations 4)solve 5)write your solution statemtn that includes inital energuy and final energuy added