A: A 21.3−g sample of dinitrogen monoxide is confined in a 5.76−L vessel. What is the pressure (in atm) at 111°C? B: Find the density of Freon−11 (CFCl3) at 157°C and 4.65 atm.
g/L = ?

A. 2.65 atm.

B. 18.11 g/L.

Explanation:

A. Determination of the pressure

Mass of N₂O = 21.3 g

Volume = 5.76 L

Temperature (T) = 111 °C

Pressure (P) =.?

First, we shall determine the number of mole in 21.3 g of dinitrogen monoxide, N₂O. This can be obtained as follow:

Mass of N₂O = 21.3 g

Molar mass of N₂O = (14×2) + 16

= 28 + 16

= 44 g/mol

Mole of N₂O =?

Mole = mass /Molar mass

Mole of N₂O = 21.3/44

Mole of N₂O = 0.484 mole

Next, we shall convert 111°C to Kelvin temperature. This can be obtained as follow:

T(K) = T(°C) + 273

Temperature (T) = 111 °C

Temperature (T) = 111 °C + 273

Temperature (T) = 384 K

Finally, we shall determine the pressure. This can be obtained as follow:

Number mole of N₂O = 0.484 mole

Volume = 5.76 L

Temperature (T) = 384 K

Gas constant (R) = 0.0821 atm.L/Kmol

Pressure (P) =.?

PV = nRT

P × 5.76 = 0.484 × 0.0821 × 384

Divide both side by 5.76

P = (0.484 × 0.0821 × 384) / 5.76

P = 2.65 atm

B. Determination of the density of CFCl₃

Temperature (T) = 157°C

Pressure (P) = 4.65 atm.

Density of CFCl₃ =?

First, we shall determine the molar mass of CFCl₃. This can be obtained as follow:

Molar mass of CFCl₃ = 12 + 19 + (35.5×3)

= 12 + 19 + 106.5

= 137.5 g/mol

Next, we shall convert 157°C to Kelvin temperature. This can be obtained as follow:

T(K) = T(°C) + 273

Temperature (T) = 157 °C

Temperature (T) = 157 °C + 273

Temperature (T) = 430 K

Finally, we shall determine the density of CFCl₃. This can be obtained as follow:

Temperature (T) = 430 K

Pressure (P) = 4.65 atm.

Molar mass of CFCl₃ (M) = 137.5 g/mol

Gas constant (R) = 0.0821 atm.L/Kmol

Density (D) of CFCl₃ =?

D = PM / RT

D = (4.65 × 137.5) / (0.0821 × 430)

D = 18.11 g/L

a rain shadow is a dry region of land on the side that is protected against the prevailing winds of a mountain range. the prevailing winds are the winds that occur most of the time in a particular place of the earth

prevailing winds carry air toward the mountain range. as the air rises up over a mountain range, the air cools, water vapor condenses, and clouds form. on this side of the mountains, called the windward side, precipitation falls in the form of  rain  or snow. this dry air produces a  rain shadow.