1.dH = Vdp + Tds is valid only if? 2.A closed system that does not change mechanical work and heat with the environment evolves spontaneously in the sense

3. An isolated system evolves spontaneously in the sense…

A. decrease in Helmholtz free energy;

B. increase in entropy;

C. decrease in enthalpy;

D. decrease in Gibbs free energy;

E. none of the answers correspond.

a is the answer

explanation:

which statement about trans-fatty acids is false?

a. the conversion of cis-fatty acids to trans-fatty acids is inhibited by the presence of antioxidants.

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hydrocarbons are organic compounds that contain only hydrogens and carbons. they can be saturated (those which contain only carbon-carbon single bonds) or unsaturated (those which contain carbon-carbon double or triple bonds) in nature. hydrocarbons can undergo several reactions like substitution, elimination etc.  

on substituting one or more hydrogen atoms in hydrocarbon it results in the formation of haloalkane. as the halogen atoms are large compared to the carbon and hydrogen atoms, due to which the molecular weight increases and the bond become polar because of presence electronegative halogen atom and results in the increase in boiling point of the haloalkane.

thus, the correct option is (b) that is the boiling point of the new compound increases on substituting a hydrogen atom with a halogen in a hydrocarbon.

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explanation:

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