Did human populations in the area depend on technological systems to acquire resources or modify the physical area of Dublin Ireland ?

Which buffer would be better able to hold a steady ph on the addition of strong acid, buffer 1 or buffer 2? explain. buffer 1: a solution containing 0.10 m nh4cl and 1 m nh3. buffer 2: a solution containing 1 m nh4cl and 0.10 m nh3