I need help with this

An exothermic reaction is conducted in an insulated calorimeter filled with water. the calorimeter is then sealed so that there is no heat exchanged between the contents of the container and the surrounding air. which of the following statements is true about the reaction?

Why do you suppose the structural polysaccharide cellulose does not contain branches? why do you suppose the structural polysaccharide cellulose does not contain branches? branches in the molecule would generate side chains that would almost certainly make it difficult to pack the cellulose molecules into globules, thereby decreasing the flexibility and strength of the globules. branches in the molecule would generate side chains that would almost certainly make it difficult to pack the cellulose molecules into microfibrils, thereby increasing the rigidity and strength of the microfibrils. branches in the molecule would generate side chains that would almost certainly make it difficult to pack the cellulose molecules into globules, thereby increasing the flexibility and strength of the globules. branches in the molecule would generate side chains that would almost certainly make it difficult to pack the cellulose molecules into microfibrils, thereby decreasing the rigidity and strength of the microfibrils.

Astudent is given a sample of a blue copper sulfate hydrate. he weighs the sample in a dry covered porcelain crucible and got a mass of 23.875 g for the crucible, lid, and sample. the mass of the empty crucible and lid was found earlier to be 22.652 g. he then heats the crucible to expel the water of hydration, keeping the crucible at red heat for 10 minutes with the lid slightly ajar. on colling, he finds the mass of crucible, lid, and contents to be 23.403 g. the sample was changed in the process to very light clue anhydrous cuso4. if there are again 100.0 g of hydrate, how many grams of cuso4 are in it? how many moles of cuso4? (hint: molar mass of cuso4 = 159.6 g / mole. what per cent of the hydrate is cuso4? you may convert the mass of cuso4 to moles.)