A liquid changes color as it cools and become solid. How can you confirm the type of change that took place?

Iam in desperate need of with this !

You are making a solution of calcium chloride dissolved in water. you add solid, stir, and it dissolves. you add just a spatula tip full, stir, and the solid does not dissolve. how could you describe the solutions before and after adding the spatula tip amount

Asample of air with a volume of 2.20m3 at a pressure of 105 kpa and a temperature of 30c is cooled to 10c and the pressure is reduced to 75.0 kpa. what is the new volume? 6.9 1.34 2.56 43.0 2.88