Draw structures for all constitutional isomers with the molecular formula C4H8 that have:
(a) Only single bonds (b) One double bond

(a)

Cyclobutane.Methylcyclopropane.

(b)

1-Butene.2-Butene (two spatial isomers.)2-Methyl-1-propene.

Refer to the diagram attached for the structures.

Explanation:

Number of rings and double bonds in each molecule

Calculate the degree of unsaturation to find the number of rings and multiple bonds (including double bonds) in those isomer molecules. The presence of each ring and each double bond would add one to the degree of unsaturation of that molecule.

Let , , , and denote the number of carbon, nitrogen, halogen, and hydrogen atoms in each isomer molecule, respectively.

The degree of unsaturation of one such molecule would be:

.

For :

(four carbon atoms in each molecule.) (no nitrogen atom.) (no halogen atom.) (eight hydrogen atoms in each molecule.)

Therefore, the degree of unsaturation of a molecule with the chemical formula would be:

.

In other words, the degree of unsaturation is for all isomers with this particular chemical formula. Therefore, each isomer would contain either a ring or a double bond, but not both.

(a)

If there is no double bond in one such molecule, there must be exactly one ring per molecule.

The minimum number of carbon atoms in a ring is three. With four carbon atoms in each molecule, there would be either a three-member ring (with one methyl group attached) or a four-member ring.

Four-membered ring with single bonds only: cyclobutane.Three-membered ring with single bonds only and one methyl group attached: methylcyclopropane. (b)

If there is one double bond in one such isomer molecule, there would not be a ring. Because of the degree of unsaturation, there would be no more than one double bond in each of these molecules.

With four carbon atoms, there are two possible backbones to consider: backbones with three carbon atoms each, and backbones with four carbon atoms each.

The backbone of those molecules might contain three carbon atoms. There would be one double bond in the backbone and one methyl group attached to the carbon atom at the center of the backbone. The corresponding isomer molecule would be 2-methyl-1-propene.

Alternatively, the backbone of those molecules might contain four carbon atoms. There are two possible locations for the double bond:

Between the first and the second carbon atoms: 1-Butene.Between the second and third carbon atoms: 2-Butene.

Notice, that the name 2-Butene refers to two distinct spatial isomers. Unlike carbon-carbon single bonds, groups on the two sides of a carbon-carbon double bond are unable to rotate relative to one another. Therefore, the first and fourth carbon atoms would either be:

on the same side of the double bond: (2Z)-2-Butene, oron opposite sides of that double bond: (2E)-2-Butene.

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