Help guys plz help me especially with 2 and 3

The melting point of sulfur is 115 °c and its boiling point is 445 °c. what state would sulfur be in at 200 °c?

Which of the following warnings would an agricultural chemist tell a farmer who wants to recycle his or her own ammonia? recycling ammonia is a difficult process that sometimes takes weeks. recycling ammonia requires a degree in biochemistry or a related field. recycling ammonia can be harmful because it is highly flammable and toxic. recycling ammonia costs too much money considering the price of the necessary chemicals.

Which of the following reactions represents an exothermic reaction? nh3(g) + 12.0 kcal ½n2(g) + 3/2 h2(g) ch4 + 2o2 co2 + 2h2o + 212,800 cal c + 2s cs2, h = 27,550 cal c(graphite) c(diamond), h = 0.45 kcal 2h2o 2h2 + o2, h = +58 kcal