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Chemistry, 26.11.2020 02:10 celestemaria0727

The Tl in a 9.57 g sample of rodenticide was oxidized to the trivalent state and treated with an unmeasured excess of Mg/EDTA solution. The reaction is T13+ + MgY2- = TIY- + Mg2+ Titration of the liberated Mg2+ required 12.5 mL of 0.03610 M EDTA. Calculate the percent T12S04 (504.8 g/mol) in the sample. Calculate conditional constant KMY’ for the formation of the EDTA complex of Fe2 at a pH of 9.0. The dissociation constants of EDTA are K1 = 1.02 x 10-2 K2 = 2.14 x 10-3 K3 = 6.92 x 10-7 K4 = 5.50 x 10-11 The formation constant for Fe2+ and EDTA complex is KMY = 2.10 x 1014

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